First of three-part series intended to get you comfortable with photochemistry and provide you with everything you need to know to get started.
Photochemistry 101, Part I: Everything You Need To Know To Get Started
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Multi-Photon Approaches to Synthetic Photochemistry
Multi-photon approaches to synthetic photochemistry expand the potential pathways to create more efficient and potentially safer reaction conditions.
Red Light Applications in Photochemistry
A number of recent red light applications in photochemistry have expanded the options available to synthetic organic chemists.
Classic Traffic Light Chemistry Experiment – Photochemistry Style
At HepatoChem, we're serious about our chemistry but we don't take ourselves too seriously. We wanted to have a little fun re-producing one of the most viral chemistry experiments found on the web... the traffic light chemistry experiment. You know...
Photocatalytic α‐Tertiary Amine Synthesis via C−H Alkylation of Unmasked Primary Amines
Abtract A practical, catalytic entry to α,α,α"trisubstituted (α"tertiary) primary amines by C-H functionalisation has long been recognised as a critical gap in the synthetic toolbox. We report a simple and scalable solution to this problem that...
Electron Donor-Acceptor (EDA) Complexes in Photochemistry
Discussion about the modern photochemical approaches using Electron Donor-Acceptor EDA complexes in synthetic organic chemistry.
A Standard Ferrioxalate Actinometer Protocol
We describe ferrioxalate actinometer protocol we use to determine photon flux in different reaction vials and photoreactors.
Determining Photon Flux Using Actinometry
Details on how we determine photon flux using actinometry measurement. Photon flux is measured for our photoreactors using different setups.
Evaluating Light Sources in Photochemistry
Learn how properly evaluating light sources in photochemistry ensures your ability to study, optimize and scale your reactions.
Carbon-Heteroatom Cross-Coupling via an Electronically Excited Nickel (II) Complex
Abstract While carbon-heteroatom cross coupling reactions have been extensively studied, many methods are specific and limited to a set of substrates or functional groups. Reported here is a method that allows for C-O, C-N and C-S cross coupling...
Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst
Abstract Tri(9-anthryl)borane was successfully applied as an organophotocatalyst for the visible-light-induced trifluoromethylation of unactivated alkenes with CF3I. The mild reaction conditions tolerated a variety of functional groups, and the...
