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Late-Stage Sulfoximidation of Electron-Rich Arenes by Photoredox Catalysis
Abstract The sulfoximine group has been reported as a versatile and beneficial functionality for pharmaceutical or agrochemical entities. Herein, we...
Photoinduced Remote Functionalization of Amides and Amines Using Electrophilic Nitrogen Radicals
Abstract The selective functionalization of C(sp3)-H bonds at distal positions to functional groups is a challenging task in synthetic chemistry....
Radical Deoxychlorination of Cesium Oxalates for the Synthesis of Alkyl Chlorides
Abstract A radical deoxychlorination of cesium oxalates has been developed for the preparation of hindered secondary and tertiary alkyl chlorides....
Air‐Stable CpCoI–Phosphite–Fumarate Precatalyst in Cyclization Reactions: Comparing Different Methods of Energy Supply
Abstract The robust CoIprecatalyst [CpCo(P{OEt}3)(trans"MeO2CHC=CHCO2Me)] was investigated in cyclotrimerizations, furnishing benzenes and pyridines...
Electrophile, Substrate Functionality, and Catalyst Effects in the Synthesis of α‐Mono and Di‐Substituted Benzylamines via Visible‐Light Photoredox Catalysis in Flow
Abstract We report herein the facile and one"pot synthesis of α"mono" and di"substituted benzylamines from cheap and readily available α"amino...
Photocatalytic reverse polarity Povarov reaction
Abstract A visible light mediated iridium photocatalysed reverse polarity Povarov reaction of aryl imines and electron deficient alkenes is...
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