{"id":25002,"date":"2019-08-07T15:15:03","date_gmt":"2019-08-07T22:15:03","guid":{"rendered":"https:\/\/hepatochem.com\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/"},"modified":"2019-08-07T15:15:03","modified_gmt":"2019-08-07T22:15:03","slug":"visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst","status":"publish","type":"post","link":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/","title":{"rendered":"Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst"},"content":{"rendered":"


\n<\/p>\n

\"\"

Trifluoromethylation using tri(9-antryl)borane<\/p><\/div>\n

Abstract<\/strong><\/p>\n

Tri(9-anthryl)borane was successfully applied as an organophotocatalyst for the visible-light-induced trifluoromethylation of unactivated alkenes with CF3<\/sub>I. The mild reaction conditions tolerated a variety of functional groups, and the reaction could be extended to perfluoroalkylations with C3<\/sub>F7<\/sub>I and C4<\/sub>F9<\/sub>I. Mechanistic studies revealed that the photoredox catalysis involves an oxidative quenching pathway.<\/p>\n

Authors:<\/strong> Jisu Moon, <\/span>Yu Kyung Moon, Do Dam Park, Sukyung Choi, Youngmin You, Eun Jin Cho*<\/strong><\/span><\/p>\n

Link:<\/strong> https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.joc.9b01624<\/a><\/p>\n

<\/body><\/html><\/p>\n","protected":false},"excerpt":{"rendered":"

Abstract Tri(9-anthryl)borane was successfully applied as an organophotocatalyst for the visible-light-induced trifluoromethylation of unactivated alkenes with CF3I. The mild reaction conditions tolerated a variety of functional groups, and the reaction could be extended to perfluoroalkylations with C3F7I and C4F9I. Mechanistic studies revealed that the photoredox catalysis involves an oxidative quenching pathway. Authors: Jisu Moon, Yu […]<\/p>\n","protected":false},"author":1,"featured_media":25003,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_et_pb_use_builder":"","_et_pb_old_content":"","_et_gb_content_width":"","_jetpack_memberships_contains_paid_content":false,"footnotes":""},"categories":[489],"tags":[],"class_list":["post-25002","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-featured-articles"],"yoast_head":"\nVisible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/\" \/>\n<meta name=\"twitter:label1\" content=\"\u00c9crit par\" \/>\n\t<meta name=\"twitter:data1\" content=\"admin\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\\\/#article\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\\\/\"},\"author\":{\"name\":\"admin\",\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/#\\\/schema\\\/person\\\/e095b8d6d9795de228233250261c2cfd\"},\"headline\":\"Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst\",\"datePublished\":\"2019-08-07T22:15:03+00:00\",\"mainEntityOfPage\":{\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\\\/\"},\"wordCount\":108,\"publisher\":{\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/#organization\"},\"image\":{\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\\\/#primaryimage\"},\"thumbnailUrl\":\"https:\\\/\\\/hepatochem.com\\\/wp-content\\\/uploads\\\/2020\\\/09\\\/jo9b01624_0012.gif\",\"articleSection\":[\"Featured Article\"],\"inLanguage\":\"fr-FR\"},{\"@type\":\"WebPage\",\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\\\/\",\"url\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\\\/\",\"name\":\"Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/#website\"},\"primaryImageOfPage\":{\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\\\/#primaryimage\"},\"image\":{\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\\\/#primaryimage\"},\"thumbnailUrl\":\"https:\\\/\\\/hepatochem.com\\\/wp-content\\\/uploads\\\/2020\\\/09\\\/jo9b01624_0012.gif\",\"datePublished\":\"2019-08-07T22:15:03+00:00\",\"inLanguage\":\"fr-FR\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\\\/\\\/hepatochem.com\\\/fr\\\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\\\/\"]}]},{\"@type\":\"ImageObject\",\"inLanguage\":\"fr-FR\",\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\\\/#primaryimage\",\"url\":\"https:\\\/\\\/hepatochem.com\\\/wp-content\\\/uploads\\\/2020\\\/09\\\/jo9b01624_0012.gif\",\"contentUrl\":\"https:\\\/\\\/hepatochem.com\\\/wp-content\\\/uploads\\\/2020\\\/09\\\/jo9b01624_0012.gif\",\"width\":500,\"height\":187,\"caption\":\"Trifluoromethylation using tri(9-antryl)borane\"},{\"@type\":\"WebSite\",\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/#website\",\"url\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/\",\"name\":\"HepatoChem\",\"description\":\"Reinventing Chemistry for Life Sciences\",\"publisher\":{\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/#organization\"},\"potentialAction\":[{\"@type\":\"SearchAction\",\"target\":{\"@type\":\"EntryPoint\",\"urlTemplate\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/?s={search_term_string}\"},\"query-input\":{\"@type\":\"PropertyValueSpecification\",\"valueRequired\":true,\"valueName\":\"search_term_string\"}}],\"inLanguage\":\"fr-FR\"},{\"@type\":\"Organization\",\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/#organization\",\"name\":\"HepatoChem\",\"url\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/\",\"logo\":{\"@type\":\"ImageObject\",\"inLanguage\":\"fr-FR\",\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/#\\\/schema\\\/logo\\\/image\\\/\",\"url\":\"https:\\\/\\\/i0.wp.com\\\/xn8.6f7.myftpupload.com\\\/wp-content\\\/uploads\\\/2019\\\/12\\\/HepatoChem-logo-lowres.png?fit=500%2C89&ssl=1\",\"contentUrl\":\"https:\\\/\\\/i0.wp.com\\\/xn8.6f7.myftpupload.com\\\/wp-content\\\/uploads\\\/2019\\\/12\\\/HepatoChem-logo-lowres.png?fit=500%2C89&ssl=1\",\"width\":500,\"height\":89,\"caption\":\"HepatoChem\"},\"image\":{\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/#\\\/schema\\\/logo\\\/image\\\/\"},\"sameAs\":[\"https:\\\/\\\/x.com\\\/evoluchem\",\"https:\\\/\\\/www.linkedin.com\\\/company\\\/2420256\"]},{\"@type\":\"Person\",\"@id\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/#\\\/schema\\\/person\\\/e095b8d6d9795de228233250261c2cfd\",\"name\":\"admin\",\"image\":{\"@type\":\"ImageObject\",\"inLanguage\":\"fr-FR\",\"@id\":\"https:\\\/\\\/secure.gravatar.com\\\/avatar\\\/c957a93c7d0c8dd066483ae6aed9fb20b222db3695bbe7f027a1baa409d44446?s=96&d=mm&r=g\",\"url\":\"https:\\\/\\\/secure.gravatar.com\\\/avatar\\\/c957a93c7d0c8dd066483ae6aed9fb20b222db3695bbe7f027a1baa409d44446?s=96&d=mm&r=g\",\"contentUrl\":\"https:\\\/\\\/secure.gravatar.com\\\/avatar\\\/c957a93c7d0c8dd066483ae6aed9fb20b222db3695bbe7f027a1baa409d44446?s=96&d=mm&r=g\",\"caption\":\"admin\"},\"url\":\"https:\\\/\\\/hepatochem.com\\\/fr\\\/author\\\/admin\\\/\"}]}<\/script>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/","twitter_misc":{"\u00c9crit par":"admin"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"Article","@id":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/#article","isPartOf":{"@id":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/"},"author":{"name":"admin","@id":"https:\/\/hepatochem.com\/fr\/#\/schema\/person\/e095b8d6d9795de228233250261c2cfd"},"headline":"Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst","datePublished":"2019-08-07T22:15:03+00:00","mainEntityOfPage":{"@id":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/"},"wordCount":108,"publisher":{"@id":"https:\/\/hepatochem.com\/fr\/#organization"},"image":{"@id":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/#primaryimage"},"thumbnailUrl":"https:\/\/hepatochem.com\/wp-content\/uploads\/2020\/09\/jo9b01624_0012.gif","articleSection":["Featured Article"],"inLanguage":"fr-FR"},{"@type":"WebPage","@id":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/","url":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/","name":"Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst","isPartOf":{"@id":"https:\/\/hepatochem.com\/fr\/#website"},"primaryImageOfPage":{"@id":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/#primaryimage"},"image":{"@id":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/#primaryimage"},"thumbnailUrl":"https:\/\/hepatochem.com\/wp-content\/uploads\/2020\/09\/jo9b01624_0012.gif","datePublished":"2019-08-07T22:15:03+00:00","inLanguage":"fr-FR","potentialAction":[{"@type":"ReadAction","target":["https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/"]}]},{"@type":"ImageObject","inLanguage":"fr-FR","@id":"https:\/\/hepatochem.com\/fr\/visible-light-induced-trifluoromethylation-of-unactivated-alkenes-with-tri9-anthrylborane-as-an-organophotocatalyst\/#primaryimage","url":"https:\/\/hepatochem.com\/wp-content\/uploads\/2020\/09\/jo9b01624_0012.gif","contentUrl":"https:\/\/hepatochem.com\/wp-content\/uploads\/2020\/09\/jo9b01624_0012.gif","width":500,"height":187,"caption":"Trifluoromethylation using tri(9-antryl)borane"},{"@type":"WebSite","@id":"https:\/\/hepatochem.com\/fr\/#website","url":"https:\/\/hepatochem.com\/fr\/","name":"HepatoChem","description":"Reinventing Chemistry for Life Sciences","publisher":{"@id":"https:\/\/hepatochem.com\/fr\/#organization"},"potentialAction":[{"@type":"SearchAction","target":{"@type":"EntryPoint","urlTemplate":"https:\/\/hepatochem.com\/fr\/?s={search_term_string}"},"query-input":{"@type":"PropertyValueSpecification","valueRequired":true,"valueName":"search_term_string"}}],"inLanguage":"fr-FR"},{"@type":"Organization","@id":"https:\/\/hepatochem.com\/fr\/#organization","name":"HepatoChem","url":"https:\/\/hepatochem.com\/fr\/","logo":{"@type":"ImageObject","inLanguage":"fr-FR","@id":"https:\/\/hepatochem.com\/fr\/#\/schema\/logo\/image\/","url":"https:\/\/i0.wp.com\/xn8.6f7.myftpupload.com\/wp-content\/uploads\/2019\/12\/HepatoChem-logo-lowres.png?fit=500%2C89&ssl=1","contentUrl":"https:\/\/i0.wp.com\/xn8.6f7.myftpupload.com\/wp-content\/uploads\/2019\/12\/HepatoChem-logo-lowres.png?fit=500%2C89&ssl=1","width":500,"height":89,"caption":"HepatoChem"},"image":{"@id":"https:\/\/hepatochem.com\/fr\/#\/schema\/logo\/image\/"},"sameAs":["https:\/\/x.com\/evoluchem","https:\/\/www.linkedin.com\/company\/2420256"]},{"@type":"Person","@id":"https:\/\/hepatochem.com\/fr\/#\/schema\/person\/e095b8d6d9795de228233250261c2cfd","name":"admin","image":{"@type":"ImageObject","inLanguage":"fr-FR","@id":"https:\/\/secure.gravatar.com\/avatar\/c957a93c7d0c8dd066483ae6aed9fb20b222db3695bbe7f027a1baa409d44446?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/c957a93c7d0c8dd066483ae6aed9fb20b222db3695bbe7f027a1baa409d44446?s=96&d=mm&r=g","contentUrl":"https:\/\/secure.gravatar.com\/avatar\/c957a93c7d0c8dd066483ae6aed9fb20b222db3695bbe7f027a1baa409d44446?s=96&d=mm&r=g","caption":"admin"},"url":"https:\/\/hepatochem.com\/fr\/author\/admin\/"}]}},"jetpack_featured_media_url":"https:\/\/hepatochem.com\/wp-content\/uploads\/2020\/09\/jo9b01624_0012.gif","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/hepatochem.com\/fr\/wp-json\/wp\/v2\/posts\/25002","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/hepatochem.com\/fr\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/hepatochem.com\/fr\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/hepatochem.com\/fr\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/hepatochem.com\/fr\/wp-json\/wp\/v2\/comments?post=25002"}],"version-history":[{"count":0,"href":"https:\/\/hepatochem.com\/fr\/wp-json\/wp\/v2\/posts\/25002\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/hepatochem.com\/fr\/wp-json\/wp\/v2\/media\/25003"}],"wp:attachment":[{"href":"https:\/\/hepatochem.com\/fr\/wp-json\/wp\/v2\/media?parent=25002"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/hepatochem.com\/fr\/wp-json\/wp\/v2\/categories?post=25002"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/hepatochem.com\/fr\/wp-json\/wp\/v2\/tags?post=25002"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}