{"id":25624,"date":"2018-07-31T17:30:51","date_gmt":"2018-08-01T00:30:51","guid":{"rendered":"https:\/\/hepatochem.com\/radical-deoxychlorination-of-cesium-oxalates-for-the-synthesis-of-alkyl-chlorides\/"},"modified":"2018-07-31T17:30:51","modified_gmt":"2018-08-01T00:30:51","slug":"radical-deoxychlorination-of-cesium-oxalates-for-the-synthesis-of-alkyl-chlorides","status":"publish","type":"post","link":"https:\/\/hepatochem.com\/euro\/radical-deoxychlorination-of-cesium-oxalates-for-the-synthesis-of-alkyl-chlorides\/","title":{"rendered":"Radical Deoxychlorination of Cesium Oxalates for the Synthesis of Alkyl Chlorides"},"content":{"rendered":"

[et_pb_section fb_built=”1″ admin_label=”section” _builder_version=”4.16″ global_colors_info=”{}”][et_pb_row admin_label=”row” _builder_version=”4.16″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” global_colors_info=”{}”][et_pb_column type=”4_4″ _builder_version=”4.16″ custom_padding=”|||” global_colors_info=”{}” custom_padding__hover=”|||”][et_pb_text admin_label=”Text” _builder_version=”4.20.4″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” hover_enabled=”0″ global_colors_info=”{}” sticky_enabled=”0″]<\/p>\n

\"\"Abstract<\/strong><\/p>\n

A radical deoxychlorination of cesium oxalates has been developed for the preparation of hindered secondary and tertiary alkyl chlorides. The reaction tolerates a number of functional groups, including ketones, alcohols, and amides, and provides complementary reactivity to standard deoxychlorination reactions proceeding by heterolytic mechanisms. Preliminary studies demonstrate that the developed conditions can also be applied to deoxybromination and deoxyfluorination reactions.<\/p>\n

Authors:<\/strong> Justin Y. Su, <\/span>Denise C. Gr\u00fcnenfelder, Kohei Takeuchi, Sarah E. Reisman*<\/strong><\/p>\n

Link:<\/strong> https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.8b02045<\/a><\/p>\n

[\/et_pb_text][\/et_pb_column][\/et_pb_row][\/et_pb_section]<\/p>\n","protected":false},"excerpt":{"rendered":"

Abstract A radical deoxychlorination of cesium oxalates has been developed for the preparation of hindered secondary and tertiary alkyl chlorides. The reaction tolerates a number of functional groups, including ketones, alcohols, and amides, and provides complementary reactivity to standard deoxychlorination reactions proceeding by heterolytic mechanisms. Preliminary studies demonstrate that the developed conditions can also be […]<\/p>\n","protected":false},"author":1,"featured_media":25625,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_et_pb_use_builder":"on","_et_pb_old_content":"\r\n\"\"Abstract<\/strong>\r\n\r\nA radical deoxychlorination of cesium oxalates has been developed for the preparation of hindered secondary and tertiary alkyl chlorides. The reaction tolerates a number of functional groups, including ketones, alcohols, and amides, and provides complementary reactivity to standard deoxychlorination reactions proceeding by heterolytic mechanisms. Preliminary studies demonstrate that the developed conditions can also be applied to deoxybromination and deoxyfluorination reactions.\r\n\r\nAuthors:<\/strong> Justin Y. Su, <\/span>Denise C. Gr\u00c3\u00bcnenfelder, Kohei Takeuchi, Sarah E. Reisman*<\/strong>\r\n\r\nLink:<\/strong> https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.8b02045<\/a><\/body><\/html>\r\n","_et_gb_content_width":"","_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_feature_clip_id":0,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_post_was_ever_published":false},"categories":[680],"tags":[],"class_list":["post-25624","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-featured-articles"],"yoast_head":"\nRadical Deoxychlorination of Cesium Oxalates for the Synthesis of Alkyl Chlorides<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/hepatochem.com\/euro\/radical-deoxychlorination-of-cesium-oxalates-for-the-synthesis-of-alkyl-chlorides\/\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"admin\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"1 minute\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\\\/\\\/hepatochem.com\\\/euro\\\/radical-deoxychlorination-of-cesium-oxalates-for-the-synthesis-of-alkyl-chlorides\\\/#article\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/hepatochem.com\\\/euro\\\/radical-deoxychlorination-of-cesium-oxalates-for-the-synthesis-of-alkyl-chlorides\\\/\"},\"author\":{\"name\":\"admin\",\"@id\":\"https:\\\/\\\/hepatochem.com\\\/euro\\\/#\\\/schema\\\/person\\\/e095b8d6d9795de228233250261c2cfd\"},\"headline\":\"Radical Deoxychlorination of Cesium Oxalates for the Synthesis of Alkyl 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